I had the same thing happen to me two weeks ago - my tap is usually 7.6-7.8, but I did a WC on my Malawi tank and all the fish started freaking out, so I stopped the flow before the refill was complete and observed their behavior for a few minutes. Then I tested the tap water and it was 6.8! The tank pH had dropped to about 7.2 from about 8. After smacking my forehead, I dumped in some Seachem buffers, and after a few minutes the fish calmed down, then finished refilling (slowly).
The fish in all my other tanks loved it, though, because they're all in planted tanks with driftwood and (in some cases) CO2, so their pH is usually 6.8-7.2 anyway, and it usually gets adjusted up some when I do WCs.
Yet another reason why I should follow George's advice from another thread and mix/age water in a barrel before adding it to tanks - your tap water can change without notice.