There are two ways to use the TDS meter. One is to use it to create a predetermined level of solids. The other is to put in the additives at their normal level and then test the water to make sure it's what you want. Start with an empty container of water. Prepare it as you would for new Malawi cichlids. Then, when it's all set, check the TDS. That's your overall benchmark. Chemical tests really don't enter into it, except for pH. I would not trust pH test kits anyway, because they're very inaccurate. Only use a calibrated pH meter.
The other way (which should be even more helpful) is to check the TDS of the water new fish are in PRIOR to putting them in your tank. A rapid swing in TDS can damage gills, so it's a good idea to slowly match the fish to your tank before putting them in.